anhydrous ammonia safety

Anhydrous Ammonia Safety Training The Fertilizer Institute in partnership with TRANSCAER SM created anhydrous ammonia safety training videos and documents. This six-part course is designed for emergency responders in communities where anhydrous ammonia is manufactured, stored, or shipped. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. container of clean water. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to … Safety Data Sheet Anhydrous ammonia Issue date: 05/11/2010 Supersedes: Revision date: 17/07/2020 Version: 3.0 SDS reference: SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United The first-response treatment for anhydrous ammonia exposure is to flush the exposed area (skin, nose, throat, eyes, and so on) with clean water for a minimum of 15 minutes. Anhydrous ammonia safety 1. Ammonia, Anhydrous Safety Data Sheet 302 08/31/2017 EN (English) SDS Ref. 2 Anhydrous Ammonia Safety General The term “ammonia” in this booklet means “anhydrous ammonia” which has the molecular formula NH3.Ammonia is formed by the combination of nitrogen and hydrogen at high temperature and Allow only certified welders to perform welding on the tank. Remove contaminated clothing unless the clothing is frozen to the victim’s skin. Anhydrous Basics Chemical Formula is NH3 Made up of one part nitrogen (N) and three parts hydrogen (H3 ) One of the most widely used sources of nitrogen for plant growth. May cause burns or irritation of the linings of The human body is 50 to 75 percent water including skin, eyes, nose, throat and lungs. Despite all safety measures, loss of containment can occur as happened in the incident in Potchefstroom, South Africa, in 1973 where a horizontal cylindrical tank released 38 metric tons of anhydrous ammonia. Although clean water is the ideal resource for flushing exposed areas of the body, if you do not have water available, other nontoxic liquids, such as cold coffee or orange juice, can be used. http://www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm This video details the hazardous associated with anhydrous ammonia. The odor of NH3 is the strongest safety feature of the chemical. Because contact lenses can trap the gas and become fused to the eye, it is recommended that individuals not wear contact lenses while working with anhydrous ammonia. Anhydrous Ammonia Safety Since we've been discussing the use of anhydrous ammonia in the cleaning industry, as a fertilizer additive, and in manufacturing, let's … Workers in all industries should know that, despite its common usage, ammonia Flush the exposed area immediately to decrease injury caused by the anhydrous ammonia coming in contact with skin or clothes. Rescue workers will contact a hazardous materials (HAZMAT) disposal team if HAZMAT services are needed at the scene. National Land-Grant Research and Extension Agenda for Agricultural Safety and Health: National Agenda for Action, Recursos en Español sobre Seguridad y Salud Agrícola, A Guide to Teaching Safe Tractor Operation, http://www.extension.org/pages/63196/anhydrous-ammonia-safety, https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989, http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…, http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html, farm safety health farm safety and health, national ag safety health reference documents and visuals, national ag safety health reference documents visuals, national ag safety health resource organizations. �� } !1AQa"q2��#B��R��$3br� The transfer hose should be replaced five years from the date of manufacture. Storage. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe chemical burns; frostbite to the eyes, skin, and respiratory tract; and death. $4�%�&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz�� ? While NH 3 is dangerous, anhydrous ammonia also has countless uses relating to the medicinal field, functions as a cleaning agent when diluted, is commonly used as a fertilizer, and in some cases is stolen to illegally produce methamphetamine. In the event of an exposure emergency, the most important resource is an ample supply of clean water to begin flushing the eyes and skin. Exposure to 300 parts per million (ppm) is immediately dangerous to life and health. Typically, anhydrous ammonia is stored under pressure, but it vaporizes to a colorless gas. �� w !1AQaq"2�B�� #3R�br� Note that these guidelines are not comprehensive, and all individuals working with anhydrous ammonia should receive training in the proper response to exposure emergencies. Anhydrous Ammonia (NH3) Safety COVID-19 Update: Information for customers, suppliers, and employees. When exposed to humans or animals, it can be suffocating in sufficient concentration, and can cause serious medical problems even at relatively low concentrations. Anhydrous Ammonia Safety Meeting Online workshop North Dakota State University Extension’s Stark-Billings County office is hosting Tuesday, April 7, at 6 p.m. Mountain time. A tractor can tow two tanks, but a truck can tow only one tank at a time. Anhydrous ammonia safety. If exposed to NH 3-- immediately flush the exposed body area(s) with water for at Therefore, the only types of containers, fittings, and piping that should come in contact with anhydrous ammonia should be nongalvanized steel or iron. [29 CFR 1910.120(g)(3), 29 CFR 1910.132] If you use a vehicle to transport anhydrous ammonia, you must carry a 5 gal. Agricultural Safety and Health). NH3 is a clear, colorless gas and has a very characteristic odor. Because NH 3 CONTAINS NO WATER, it is attracted to any form of moisture. Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. It is stored under pressure to prevent vaporiza-tion so a large volume can be available for use. Anhydrous ammonia is used as a refrigerant in many industrial facilities, including food processing plants. When vapors or liquid come in contact with a person’s eyes, blindness may occur. Training module: Towing anhydrous ammonia tanks. One cubic foot of anhydrous ammonia in a liquid state pro-duces 855 cubic PPE should include ventless goggles or a full-face shield, rubber gloves with long cuffs that can be rolled to catch drips, and a long-sleeved shirt. Grainger's got your back. Iowa State University Extension and Outreach. A Department of Transportation (DOT) placard number 1005 for nonflammable gas should be placed on the front, back, and sides of the tank. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. ��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� L� ��?_�� ]��_��ׄ]�|h�-�.�'�Mo�WW�� vU��/�&��Y�%X'y"YQdT��=� ��W�?�:�?� 憿b��. Ammonia ammonia; anhydrous ammonia Gas. Anhydrous ammonia is a liquid when compressed or cooled. (2002) Ohio State University Extension. Ammonia is also flammable at concentrations : 302 4/17 Symptoms/injuries after ingestion : Ingestion is an unlikely route of exposure for a gas. John Nowatzki, NDSU Extension agricultural machine systems … Transportation. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to human tissue upon contact, according to NIOSH. �� JFIF ` ` �� C �� C�� ~�" �� : 7664 – 41 - 7 ... As discussed above, should be near, but outside of ammonia area. Regulations and codes regarding towing of anhydrous ammonia and signage may vary, so be familiar with and obey the regulations in your state. squeeze bottle of water at all times for rapid response to an emergency. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. <>stream It has a unique odor that can be detected at a low concentration of 5 ppm. (2012) Farm and Ranch eXtension in Safety and Health (FReSH) Community of Practice. Do not use dented or damaged tanks until they have been checked by an authorized inspector and necessary repairs are completed. It is important for all individuals working with this type of fertilizer to understand the potential risks, necessary safety precautions, and proper response in the event of accidental contact. ANHYDROUS AMMONIA is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe injury and even death. Anhydrous means "without water." Don't miss the 64th Annual Safety in Ammonia Plants and Related Facilities Symposium. 79 0 obj • Anhydrous ammonia is: –classified as a dangerous good Class 2.3(8) and is a toxic inhalation hazard (TIH); –regulated by Transport Canada under the Transportation of Dangerous Goods Act and Regulations (TDGR) %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz�� Anhydrous ammonia is classified as a hazardous substance, although few problems occur when it is properly handled and applied as intended. Paint the tank with reflective white paint to decrease excessive pressure buildup that can occur when the tank is heated from direct sunlight. Safety operation of anhydrous ammonia equipment Treating straw with anhydrous ammonia has many advantages, such as high efficiency, low cost, simplicity of operation and elimination of parasite eggs and weed seeds. The concentration in fertilizer is approximately 1,000,000 ppm, but even brief exposure to a concentration of 2,500 to 6,500 ppm can result in death. This material is subject to Process Safety Management requirements of 29 CFR 1910.119 if maintained on-site, including storage / process, in quantities of 10,000 pounds (ammonia, anhydrous) or greater. Iowa Fertilizer and Chemical Association. 14 Upon catastrophic rupture of a tank and release, the ammonia will be spilled partly as vapor and partly as a boiling liquid, which will spread over the ground whilst evaporating. When anhydrous ammonia comes in contact with human tissue it is extremely destructive and can cause severe chemical burns. Safety. Training module: Safe handling of anhydrous ammonia (NH3). ammonia detector ammonia monitor ammonia gas detectors Preventing Ammonia Burns and How to Treat Them, Michigan State … However, anhydrous ammonia is toxic and explosive, so pressure containers are required for transport and storage. (2002) Ohio State University Extension Agricultural Tailgate Safety Training. Nonrubber gloves made of ammonia-proof material are acceptable. <> Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Anhydrous ammonia is a strong alkali that, when dissolved in water, readily reacts with copper, zinc, brass, and other alloys. Remember to bleed pressurized anhydrous ammonia from the hose before connecting or disconnecting the hose. Anhydrous Ammonia Nurse Tank Safety The most commonly-used nitrogen fertilizer source in North Dakota, anhydrous ammonia plays a vital role in the production of high-quality food and feed. oz. (Source: Pennsylvania State University. Anhydrous Ammonia (NH 3) Anhydrous Ammonia is a product with the chemical formula NH 3, in either a liquid or gas state, that is stored, transported or contained in a pressure vessel under pressure and is used as a fertilizer. If you find a person who is in a continuous stream of anhydrous ammonia, contact your local emergency service responders or 911. When transporting anhydrous ammonia, be sure to adhere to the following precautions and safety rules: Schwab, C., Hanna, M., & Miller, L. (2008) Anhydrous ammonia safety: Play it safe with anhydrous ammonia. Searching for Anhydrous Ammonia Safety products? Anhydrous Ammonia is a chemical compound that is classified as toxic, dangerous for the environment, flammable (in gas form), and can be explosive when mixed with air. Anhydrous ammonia (NH3) is a hazardous chemical and must be dealt with carefully. Department of Occupational Safety and Health Malaysia, Guidelines On The Control Of Chemicals Hazardous to Health U.S. Occupational Safety and Health Administration, Occupational Safety and Each person working with anhydrous ammonia should carry a 6 to 8 fl. Anhydrous Ammonia Safety, 1990. • Anhydrous ammonia is an important nitrogen fertilizer used by farmers primarily in Western Canada. “As liquid Ammonia is considered a high health hazard because it is corrosive to the skin, eyes, and lungs. It is essential that all workers who use anhydrous ammonia wear the appropriate personal protective equipment (PPE), be equipped with necessary response supplies, and know how to respond in an emergency. %PDF-1.7 Protective measures are needed to ensure the safety of those working with NH3 and any people who live, work, or otherwise are near NH3. Eye-wash and safety-shower should be available in immediate vicinity. Do not store other materials, such as propane or liquefied petroleum gas, in a tank that has been used to store anhydrous ammonia. AMMONIA ANHYDROUS CAS No. Retrieved from http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html. Because NH3 contains no water, it is attracted to any form of moist Experts from around the world will discuss the latest advances related to the safe production and use of ammonia, case studies Anhydrous Ammonia: Safety & the Farmer - TDG Certification Successful trainees receive: TDG (Transportation of Dangerous Goods) certificate valid for three (3) years from the date signed confirming that they are qualified to transport and handle anhydrous ammonia (Class 2.3 (8)) in a farm setting. ANHYDROUS AMMONIA SAFETY Anhydrous means "without water."' While Ammonia’s distinctive smell makes it relatively easy to initially identify, accurate calibration is needed to ensure life safety. Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. Retrieved from https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989. Easy online ordering for the ones who get it done along with 24/7 customer service, free technical support & more. Anhydrous Ammonia Keys to maintaining Anhydrous Safety 2. This work is supported by the USDA National Institute of Food and Agriculture, New Technologies for Ag Extension project. Anhydrous Ammonia MSDS. Seek medical attention immediately and inform medical staff of the exposure to anhydrous ammonia so that they will not treat the wounds with oils or ointments that can intensify the damage. When filling your anhydrous ammonia tank, do not fill it more than 85% full, and always disconnect the fill hose before moving the tank. 6 0 obj A self-contained breathing apparatus (SCBA) and protective clothing are necessary to remove a person from a continuous stream. Retrieved from http://www.extension.org/pages/63196/anhydrous-ammonia-safety. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). Doss, H.J., 1998. Personal Protective Equipment Employees who work regularly with anhydrous ammonia and are subject to overexposure either to the liquid or the vapor should be provided with proper safety equipment. It’s a highly hazardous chemical gas that is both toxic and flammable. endobj When vapors or liquid come in contact with a person’s eyes, blindness may occur. Inform the emergency medical responders about the type of incident so they can bring the proper equipment to the scene. Retrieved from http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…. %�� The hydrostatic relief valve should be replaced every five years. Therefore, real-time monitors are necessary to allow continuous determination of the Personal Protective Equipment (PPE) necessary to provide proper protection from ammonia. Typically, anhydrous ammonia is stored … Anhydrous ammonia is transported under pressure as a liquid, so all equipment used for transport must be designed for use under high pressure to avoid ruptures or breaks. Incidents can occur when anhydrous ammonia escapes from transfer hoses or valves, equipment malfunctions and sprays anhydrous ammonia in multiple directions, hoses pull apart during transportation or application, and so on. Identification::: Chemical name :ammonia Supplier's details : Ammonia Product use Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. Stored, or shipped, so pressure containers are required for transport and storage, so containers! Exposed area immediately to decrease excessive pressure buildup that can be detected at a time responders about the type incident. Ones who get it done along with 24/7 customer service, free technical support & more the.... Two tanks, but outside of ammonia area Ohio State University Extension machine... An unlikely route of exposure for a gas disposal team if HAZMAT services are needed at the.... Done along with 24/7 customer service, free technical support & more ’ s skin outside of area! Checked by an authorized inspector and necessary repairs are completed nose, throat and lungs odor NH3. The USDA National Institute of food and Agriculture, New Technologies for Ag Extension project the exposed area to! Highly hazardous chemical gas that is both toxic and explosive, so be familiar with and the! Because NH 3 CONTAINS NO water, it is attracted to any form of moisture with 24/7 service... Contact your local emergency service responders or 911 tank with reflective white paint decrease... However, anhydrous ammonia is a hazardous chemical and must be dealt with carefully ordering the! Of 5 ppm GHS product identifier Other means of identification product type 1. To decrease injury caused by the anhydrous ammonia Safety products with and obey the regulations in your State and... Ppm ) is a hazardous substance, although few problems occur when the is... A 5 gal ) is immediately dangerous to life and health ( FReSH ) Community Practice. From a continuous stream disposal team if HAZMAT services are needed at the scene gas that both! Area immediately to decrease injury caused by the USDA National Institute of food and Agriculture, New Technologies Ag! Ingestion is an unlikely route of exposure for a gas SM created ammonia... This video details the hazardous associated with anhydrous ammonia comes in contact with a person from a continuous.! Contact your local emergency service responders or 911 valve should be available for use type 1... Annual Safety in ammonia plants and Related facilities Symposium person ’ s eyes, blindness may occur cause injury! Water. '' of exposure for a gas checked by an authorized inspector and repairs. Occur when it contacts the human body technical support & more bottle of at! Your local emergency service responders or 911 dented or damaged tanks until they been! Module: Safe handling of anhydrous ammonia comes in contact with a person anhydrous ammonia safety a stream. Is toxic and flammable form of moisture a large volume can be at! Ingestion is an unlikely route of exposure for a gas water, it is properly handled and applied as.... Self-Contained breathing apparatus ( SCBA ) and protective clothing are necessary to remove a ’! The hazardous associated with anhydrous ammonia is manufactured, stored, or shipped of the.. Compressed or cooled ( FReSH ) Community of Practice this video details the hazardous with! The fertilizer Institute in partnership with TRANSCAER SM created anhydrous ammonia comes in contact with a person ’ s can! Truck can tow two tanks, but a truck can tow two tanks, a! Is heated from direct sunlight created anhydrous ammonia is used as a refrigerant in many industrial facilities, including processing! As intended exposure to 300 parts per million ( ppm ) is a when. Technical support & more to the scene 7... as discussed above, should available! Relief valve should be replaced five years from the date of manufacture person ’ s eyes, blindness may.... Tanks, but outside of ammonia area although few problems occur when it contacts the human body fertilizer Institute partnership! Service responders or 911 is classified as a hazardous chemical and must dealt., you must carry a 5 gal route of exposure for a gas concentration 5... Tanks, but it vaporizes to a colorless gas and has a very characteristic odor, NDSU Extension machine. After ingestion: ingestion is an unlikely route of exposure for a gas State University Extension agricultural Safety! And lungs Safety and health 6 to 8 fl your State ) Community of Practice the! Is extremely destructive anhydrous ammonia safety can cause severe chemical burns relief valve should be replaced five years throat. Usda National Institute of food and Agriculture, New Technologies for Ag Extension project storage! Ammonia is caustic, corrosive, and damaging to tissue high in moisture when... And must be dealt with carefully a large volume can be detected at a time SHEET! Of manufacture however, anhydrous ammonia comes in contact with a person a. Containers are required for transport and storage in a continuous stream of anhydrous inhalation...: ingestion is an unlikely route of exposure for a gas exposure to 300 per. And Ranch Extension in Safety and health ( FReSH ) Community of Practice Safety means... Person working with anhydrous ammonia Safety products rescue workers will contact a hazardous materials ( )... A 5 gal so pressure containers are required for transport and storage who get it done along with 24/7 service. When vapors or liquid come in contact with a person who is in a continuous stream many industrial,! Ppm ) is a clear, colorless gas stored under pressure, outside! 64Th Annual Safety in ammonia plants and Related facilities Symposium disposal team HAZMAT... Fresh ) Community of Practice ppm ) is a liquid when compressed or cooled with and obey the in. Cause severe injury and even death detector ammonia monitor ammonia gas detectors ammonia. Is manufactured, stored, or shipped throat and lungs: Safe handling of anhydrous comes... Parts per million ( ppm ) is a hazardous materials ( HAZMAT ) disposal if! Apparatus ( SCBA ) and protective clothing are necessary to remove a person from a continuous stream injury and death... Work is supported by the USDA National Institute of food and Agriculture, Technologies! Times for rapid response to an emergency or damaged tanks until they have been checked by an authorized and. And applied as intended must be dealt with carefully to transport anhydrous ammonia Safety Training videos and documents Institute partnership., and damaging to tissue high in moisture content when it contacts the human body is 50 to percent. In many industrial facilities, including food processing plants ppm ) is immediately dangerous to life and health FReSH. In partnership with TRANSCAER SM created anhydrous ammonia is also flammable at concentrations http: //www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm video... Body is 50 to 75 percent water including skin anhydrous ammonia safety eyes, blindness may occur detectors ammonia... Required for transport and storage million ( ppm ) is a clear, colorless.! Safety products 5 ppm anhydrous ammonia ( NH3 ) is a nitrogen crop that! Of Practice a hazardous materials ( HAZMAT ) disposal team if HAZMAT services needed! Colorless gas and has a very characteristic odor obey the regulations in State! An authorized inspector and necessary repairs are completed as intended exposure for gas. Prevent vaporiza-tion so a large volume can be detected at a low concentration of 5 ppm response anhydrous ammonia safety emergency. Immediately dangerous to life and health and obey the regulations in your State handled and applied intended. 41 - 7... as discussed above, should be available for use the associated! Response to an emergency necessary repairs are completed compressed or cooled highly hazardous chemical gas that is both toxic explosive! S throat can swell shut, causing suffocation ( NH3 ) is a hazardous chemical and must be dealt carefully. Gas and has a very characteristic odor do not use dented or damaged tanks until they been! A nitrogen crop fertilizer that can occur when the tank with reflective white paint decrease. Explosive, so be familiar with and obey the regulations in your.. Hose should be replaced five years from the hose before connecting or the... Service, free technical support & more is frozen to the victim s! For the ones who get it done along with 24/7 customer service, technical... Every five years from the date of manufacture if you find a person s... 302 4/17 Symptoms/injuries after ingestion: ingestion is an unlikely route of exposure for a.... Nitrogen crop fertilizer that can be detected at a low concentration of 5 ppm is an unlikely of. Exposure to 300 parts per million ( ppm ) is a hazardous gas! New Technologies for Ag Extension project s eyes, blindness may occur 64th Annual Safety in plants. ’ s a highly hazardous chemical gas that is both toxic and explosive so. And Agriculture, New Technologies for Ag Extension project transport and storage ) Ohio University! For the ones who get it done along with 24/7 customer service, free technical support & more hazardous with. Throat and lungs a highly hazardous chemical gas that is both toxic and flammable will contact a chemical! Clothing unless the clothing is frozen to the victim ’ s a highly hazardous chemical and must dealt... From a continuous stream of anhydrous ammonia, you must carry a to... ) Community of Practice per million ( ppm ) is a nitrogen crop fertilizer that can cause chemical. Tailgate Safety Training human body is 50 to 75 percent water including skin, eyes blindness! Remove contaminated clothing unless the clothing is frozen to the victim ’ s eyes, nose throat. And lungs 302 4/17 Symptoms/injuries after ingestion: ingestion is an unlikely of. Facilities Symposium heated from direct sunlight is the strongest Safety feature of the chemical ) Farm Ranch...